The Grainger College of Engineering
EFRC for Regenerative Energy-Efficient Manufacturing of Thermoset Polymeric Materials (REMAT)

Publications

REMAT Publication also on Google Scholar

  1. Zhang, S. ;  Xu, Z. ; Husted, K. E. L.;Lundberg, D. J.;Brown, C. M.; Wang, Y. ; Shieh, P.; Ko, K. ; Moore, J. S. ; Johnson, J. A. Cleavable Strand-Fusing Cross-linkers as Additives for Chemically Deconstructable Thermosets with Preserved Thermomechanical Properties. Angew. Chem. Int. Ed. 2025.
  2. Ko, K.; Mejia, E. B.; Fowler, H. E.; Nguyen, S. T.; AlFaraj, Y.; Wang, Y.; Leguizamon, S. C.; Sottos, N. R.; Johnson, J. A. Multi-Generation Recycling of Thermosets Enabled by Fragment Reactivation. J. Am. Chem. Soc. 2025.
  3. Liu, Q.; Cai, P.; Abueidda, D.; Vyas, S.; Koric, S.; Gomez-Bombarelli, R.; Geubelle, P. H. Univariate Conditional Variational Autoencoder for Morphogenic Pattern Design in Frontal Polymerization-based Manufacturing. Comput. Methods Appl. Mech. Eng. 2025, 438 B, 117848.
  4. Xu, Z.; Wang, K.; Suslick, B. A.; Moore, J. S. Circular Workflow for Thermosets: Activatable Repeat Unit Design for Regenerative Frontal Polymerization. J. Am. Chem. Soc., 2025.
  5. Kim, Y. S.; Zhu, M.; Hossain, M. T.; Sanders, D.; Shah, R.; Moore, J. S.; Sottos, N. R.: Ewoldt, R. H.; Geubelle, P. H.; Tawfick, S. H. Morphogenic Growth 3D Printing. Adv. Mater., 2025, 2406265.
  6. Tawfick, S.; Arretche, I. Not-So-Fragile Matter. J. Sci., 2025, 387, 6731, 250-251.
  7. Hossain, M. T.; Macosko, C. W.; McKinley, G. H., Ewoldt, R. H. Instrument Stiffness Artifacts: Avoiding Bad Data with Operating Limit Lines for Gmax and Emax. Rheol. Acta, 2025, 64, 67-79.
  8. Hossain, M. T.; Tiwari, R.; Ewoldt, R. H. Protorheology in Practice: Avoiding Misinterpretation. Curr. Opin. Colloid Interface Sci., 2024, 74, 101866.
  9. Paul, J. E.; Gao, Y.; Go, Y. K.; Rodriguez Koett, L. E.; Sharma, A.; Chen, M.; Lessard, J. J.; Topkeya, T.; Leal, C.; Moore, J. S.; Geubelle, P. H.; Sottos, N. R. Controlled Patterning of Crystalline Domains by Frontal Polymerization. Nature, 2024, 634, 85-90.
  10. Bistri, D.; Arretche, I.; Lessard, J. J.; Zakoworothny, M.; Vyas, S.; Rongy, L.; Gomez-Bombarelli, R.; Moore, J. S.; Geubelle, P. H. A Mechanism-Based Reaction-Diffusion Model for Accelerated Discovery of Thermoset Resins Frontally Polymerized by Olefin Metathesis. J. Am. Chem. Soc., 2024, 146, 31, 21877-21888.
  11. Xu, Z.; Chua, L.; Singhal, A.; Krishnan, P.: Lessard, J. L.; Suslick, B. A.; Chen, V.; Sottos, N. R.; Gomez-Bombarelli, R.; Moore, J. S. Reactive Processing of Furan-Based Monomers via Frontal Ring-Opening Metathesis Polymerization for High Performance Materials. Adv. Mater. 2024, 2405736.
  12. McFadden, T. P.; Cope, R. B.; Muhlestein, R.; Layton, D. J.; Lessard, J. J.; Moore, J. S.; Sigman, M. S. Using Data Science Tools to Reveal and Understand Subtle Relationships of Inhibitor Structure in Frontal Ring-Opening Metathesis Polymerization.  J. Am. Chem. Soc., 2024, 146, 24, 16375-16380.
  13. Lundberg, D. J.; Ko, K.; Kilgallon, L. J.; Johnson, J. A. Defining Reactivity-Deconstructability Relationships for Copolymerizations Involving Cleavable Comonomer Additives. ACS Macro Lett., 2024, 13, 5, 521-527.
  14. Liu, Q.; Abueidda, D.; Vyas, S.; Gao, Y.; Koric, S.; Geubelle, P. H. Adaptive Data-Driven Deep-Learning Surrogate Model for Frontal Polymerization in Dicyclopentadiene. J. Phys. Chem. B, 2024, 128, 5, 1220-1230. 
  15. Lessard, J. J.; Mejia, E.; Kim, A.; Zhang, Z.; Berkey, M.; Medina-Barreto, Z.; Ewoldt, R. H.; Sottos, N. R.; Moore, J. S. Unraveling Reactivity Differences: Room Temperature Ring-Opening Metathesis Polymerization (ROMP) vs. Frontal ROMP.  J. Am. Chem. Soc. 2024, 146, 11, 7216-7221.
  16. Hossain, M. T; Ewoldt, R. H. Protorheology. Journal of Rheology, 2024, 68, 1, 113-144.
  17. Wang, H. M.; Suslick, B. A.;  Lessard, J. J.; Yu, C. H.; Saengow, C.; Ewoldt, R. H.; Moore, J. S. Frontal Polymerization of Stereoisomers: Distinct Microstructures and Properties in Endo- and Exo-Dicyclopentadiene Thermosets. Macromolecules, 2024, 57, 1, 142-149.
  18. Davydovich, O; Greenlee, A. J.; Root, H. D.; Jansen, A. L.; Gallegos, S. C.; Warner, M. J.; Kent, M. S.; Cardenas, J. A.; Appelhans, L. N.; Roach, D. J.; Jones, B. H.; Leguizamon, S. C. Encapsulated Transition Metal Catalysts Enable Long Term Stability in Frontal Polymerization Resins. Macromolecules, 2023, 56, 18, 7543-7550. 
  19. AlFaraj, Y. S.; Mohapatra, S.; Shieh, P.; Husted, K. E. L.; Ivanoff, D. G.; Lloyd, E. M.; Cooper, J. C.; Dai, Y.; Singhal, A. P.; Moore, J. S.; Sottos, N. R.; Gomez-Bombarelli, R.; Johnson, J. A. A Model Ensemble Approach Enables Data-Driven Property Prediction for Chemically Deconstructable Thermosets in the Low Data Regime. ACS Cent. Sci., 2023, 9, 9, 1810-1819.
  20. Davydovich, O.; Paul, J. E.; Feist, J. D.; Aw, J. E.; Balta Bonner, F. J.; Lessard, J. J.; Tawfick, S.; Xia, Y.; Sottos, N. R.; Moore, J. S. Frontal Polymerization of Dihydrofuran Comonomer Facilitates Thermoset Decontruction. Chemistry of Materials, 2023, 34, 8790-8797. 
  21. Suslick, B. A.; Hemmer, J.; Groce, B. R.; Stawiasz, K. J.; Geubelle, P. H.; Malucelli, G.; Mariani, A.; Moore, J. S.; Pojman, J. A.; Sottos, N. R. Frontal Polymerizations: From Chemical Perspectives to Macroscopice Properties and Applications. Chem. Rev., 2023, 123, 3237-3298.
  22. Suslick, B. A.; Klok, H.-A.; Moore, J. S. There is Signal in Your Noise: A Case for Advanced Mass Analysis. ACS Polym. Au., 2022, 2, 392-396.
  23. Suslick, B. A.; Alzate-Sanchez, D. M.; Moore, J. S. Scalable Frontal Oligomerization: Insights from Advanced Mass Analysis. Macromolecules, 2022, 55, 8234-8241.