The Grainger College of Engineering
EFRC for Regenerative Energy-Efficient Manufacturing of Thermoset Polymeric Materials (REMAT)

Publications

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REMAT Journal Publications

  1. Zhou, Y.; Xu, Zhenchuang; Moore, J. S. Dual C-H Functionalization of Polyolefins for Covalent Adaptable Network Formation Via Cooperative Electrolysis. Nat. Synth. 2025.
  2. Cramblitt, A. C.; Paul, J. E.; Price, T. C.; Kaur, P.; Moore, J. S.; Sottos, N. R.; Lessard, J. J. Chemical Activation of Frontal Ring-Opening Metathesis Polymerization. ACS Macro Lett., 2025, 14, 8, 1182-1188.
  3. Lee, Y. B.; Kim, Y. S.; Chen, C.; Hossain, M. T.; Suslick, B. A.; Ewoldt, R. H.; Tawfick, S. H.; Moore, J. S.; Sottos, N. R.; Braun, P. V. Multimaterial 3D Printing in Activating Bath Enables In Situ Polymerization of Thermosets with Intricate Geometries and Diverse Elastic Behaviors. Adv. Mater., 2025, e08568.
  4. Zhu, M.; Sanders, D. M.; Kim, Y. S.; Shah, R.; Hossain, M. T.; Ewoldt, R. H.; Tawfick, S. H.; and Geubelle, P. H. Curvature Effects in the Reaction-diffusion System Governing Frontal Polymerization. Phys. Rev. E, 112, 025410, 2025.
  5. Darby, D. R.; Greenlee, A. J.; Bean, R. H.; Fairchild, D. C.; Rodriguez, V. C.; Jansen, A. L.; Gallegos, S. C.; Ramirez, S. P.; Moore, J. S.; Leguizamon, S. C.; Appelhans, L. N. Active Light-Controlled Frontal Ring-Opening Metathesis Polymerization. Nat. Commun., 16, 6291, 2025.
  6. Xu, Z.; Bean, R. H.; Hauslanden, M. M.; Leguizmon, S. C.; Moore, J. S.; Appelhans, L. N. Rapid Synthesis of Naphthols through a Photocontrolled Approach. Org. Lett., 27, 28, 7552-7557, 2025.
  7. Bagare, S. V.; Lee, M. J.; Kuehnle, A.; Moore, J. S; Baur, J. W. Initiator-Driven Tailoring of Reactivity and Inhibition in Frontally Polymerized Dicyclopentadiene-Co-Dihydrofuran Thermosets. J. Polymer Sci., 2025.
  8. Mejia, E. B.; McDougall, L.; Gonsalves, N.; Darby, D. R.; Greenlee, A. J.; Commisso, A.; Johnson, J. A.; Sottos, N. R.; Appelhans, L. N.; Cook, A. W.; Leguizamon, S. C., Roach, D. J. Real-time Process Monitoring and Automated Control for Direct Ink Write 3D Printing of Frontally Polymerizing Thermosets. npj Adv. Manuf., 2, 18, 2025.
  9. Bistri, D.; Cramblitt, A.; Arretche, I.; Zhang, C.; Cope, R. B.; Zakoworotny, M.; Mills, M. G.; Rodriguez Koett, L. E.; Chua, L.; Gomez-Bombarelli, R.; Tawfick, S. H.; Sottos, N. R.; Moore, J. S.; Geubelle, P. H. Equilibrium-Gated Pattern Formation: How Molecular Dissociation Thermodynamics Drive Emergent Behavior in Dissipative Polymeric Systems. PNAS, 2025, e2503176122.
  10. Luo, X.; Kim, Y. M.; Lee, M. J.; Mejia, E. B.; Shi, Y.; Sottos, N. R.; Baur, J. W.; Xia, Y. Multi-Generational Frontal Curing and Chemical Recycling of Polydicyclopentadiene Thermosets. Adv. Mater., 2025, 2505141.
  11. Marsh, M. C.; Hossain, M. T.; Ewoldt, R. H. Egg Yolk as a Model for Gelation: From Rheometry to Flow Physics. Phys. Fluids., 37, 043114.
  12. Krishnan, P; Lessard, J. J.; Moore, J. S.; Sottos, N. R. Rapid Gelation of Dicyclopentadiene Resins for Additive Manufacturing of Thermoset Polymers. ACS Macro Lett., 2025, 14, 5, 570-575.
  13. Arretche, I.; Lessard, J. J.; Kaur, P.; Mills, M. G.; Kim, A. J.; Liu, H. J.; Cooper, J. C.; Ewoldt, R. H.; Moore, J. S.; Tawfick, S. Active Learning Guided Optimization of Frontal Ring-Opening Metathesis Polymerization via Alkylidene Modification. ACS Macro Lett., 2025, 14, 5, 525-531.
  14. Zhang, S.;  Xu, Z.; Husted, K. E. L.; Lundberg, D. J.; Brown, C. M.; Wang, Y.; Shieh, P.; Ko, K.; Moore, J. S.; Johnson, J. A. Cleavable Strand-Fusing Cross-Linkers as Additives for Chemically Deconstructable Thermosets with Preserved Thermomechanical Properties. Angew. Chem. Int. Ed., 2025, e202500104.
  15. Ko, K.; Mejia, E. B.; Fowler, H. E.; Nguyen, S. T.; AlFaraj, Y.; Wang, Y.; Leguizamon, S. C.; Sottos, N. R.; Johnson, J. A. Multi-Generation Recycling of Thermosets Enabled by Fragment Reactivation. J. Am. Chem. Soc., 2025, 147, 15, 12503-12510.
  16. Liu, Q.; Cai, P.; Abueidda, D.; Vyas, S.; Koric, S.; Gomez-Bombarelli, R.; Geubelle, P. H. Univariate Conditional Variational Autoencoder for Morphogenic Pattern Design in Frontal Polymerization-based Manufacturing. Comput. Methods Appl. Mech. Eng., 2025, 438 B, 117848.
  17. Xu, Z.; Wang, K.; Suslick, B. A.; Moore, J. S. Circular Workflow for Thermosets: Activatable Repeat Unit Design for Regenerative Frontal Polymerization. J. Am. Chem. Soc., 2025, 147, 10, 8732-8740.
  18. Kim, Y. S.; Zhu, M.; Hossain, M. T.; Sanders, D.; Shah, R.; Moore, J. S.; Sottos, N. R.: Ewoldt, R. H.; Geubelle, P. H.; Tawfick, S. H. Morphogenic Growth 3D Printing. Adv. Mater., 2025, 2406265.
  19. Tawfick, S.; Arretche, I. Not-So-Fragile Matter. J. Sci., 2025, 387, 6731, 250-251.
  20. Hossain, M. T.; Macosko, C. W.; McKinley, G. H.; Ewoldt, R. H. Instrument Stiffness Artifacts: Avoiding Bad Data with Operating Limit Lines for Gmax and Emax. Rheol. Acta., 2025, 64, 67-79.
  21. Hossain, M. T.; Tiwari, R.; Ewoldt, R. H. Protorheology in Practice: Avoiding Misinterpretation. Curr. Opin. Colloid Interface Sci., 2024, 74, 101866.
  22. Lundberg, D. J.; Kilgallon, L. J.; Cooper, J. C.; Starvaggi, F.; Xia, Y.; Johnson, J. A. Accurate Determination of Reactivity Ratios for Copolymerization Reactions with Reversible Propagation Mechanism. Macromol., 2024, 57, 14, 6727-6740.
  23. Paul, J. E.; Gao, Y.; Go, Y. K.; Rodriguez Koett, L. E.; Sharma, A.; Chen, M.; Lessard, J. J.; Topkeya, T.; Leal, C.; Moore, J. S.; Geubelle, P. H.; Sottos, N. R. Controlled Patterning of Crystalline Domains by Frontal Polymerization. Nature, 2024, 634, 85-90.
  24. Hausladen, M. M.; Baca, E.; Nogalas, K. A.; Appelhans, L. N.; Kaehr, B.; Hamel, C. M.; Leguizamon, S. C. Volumetric Additive Manufacturing of Dicyclopentadiene by Solid-State Photopolymerization. Adv. Sci., 2024, 11, 34, 2402385.
  25. Bistri, D.; Arretche, I.; Lessard, J. J.; Zakoworothny, M.; Vyas, S.; Rongy, L.; Gomez-Bombarelli, R.; Moore, J. S.; Geubelle, P. H. A Mechanism-Based Reaction-Diffusion Model for Accelerated Discovery of Thermoset Resins Frontally Polymerized by Olefin Metathesis. J. Am. Chem. Soc., 2024, 146, 31, 21877-21888.
  26. Xu, Z.; Chua, L.; Singhal, A.; Krishnan, P.: Lessard, J. L.; Suslick, B. A.; Chen, V.; Sottos, N. R.; Gomez-Bombarelli, R.; Moore, J. S. Reactive Processing of Furan-Based Monomers via Frontal Ring-Opening Metathesis Polymerization for High Performance Materials. Adv. Mater., 2024, 2405736.
  27. McFadden, T. P.; Cope, R. B.; Muhlestein, R.; Layton, D. J.; Lessard, J. J.; Moore, J. S.; Sigman, M. S. Using Data Science Tools to Reveal and Understand Subtle Relationships of Inhibitor Structure in Frontal Ring-Opening Metathesis Polymerization.  J. Am. Chem. Soc., 2024, 146, 24, 16375-16380.
  28. Lundberg, D. J.; Ko, K.; Kilgallon, L. J.; Johnson, J. A. Defining Reactivity-Deconstructability Relationships for Copolymerizations Involving Cleavable Comonomer Additives. ACS Macro Lett., 2024, 13, 5, 521-527.
  29. Liu, Q.; Abueidda, D.; Vyas, S.; Gao, Y.; Koric, S.; Geubelle, P. H. Adaptive Data-Driven Deep-Learning Surrogate Model for Frontal Polymerization in Dicyclopentadiene. J. Phys. Chem. B., 2024, 128, 5, 1220-1230. 
  30. Kilgallon, L. J.; McFadden, T. P.; Sigman, M. S.; Johnson, J. A. Tricyclononenes and Tricyclononadienes as Efficient Monomers for Controlled ROMP: Understanding Structure-Propagation Rate Relationships and Enabling Facile Post-Polymerization Modification. Chem Sci., 2024, 15, 8334-8345.
  31. Lessard, J. J.; Mejia, E.; Kim, A.; Zhang, Z.; Berkey, M.; Medina-Barreto, Z.; Ewoldt, R. H.; Sottos, N. R.; Moore, J. S. Unraveling Reactivity Differences: Room Temperature Ring-Opening Metathesis Polymerization (ROMP) vs. Frontal ROMP.  J. Am. Chem. Soc. 2024, 146, 11, 7216-7221.
  32. Hossain, M. T; Ewoldt, R. H. Protorheology. Journal of Rheology, 2024, 68, 1, 113-144.
  33. Wang, H. M.; Suslick, B. A.;  Lessard, J. J.; Yu, C. H.; Saengow, C.; Ewoldt, R. H.; Moore, J. S. Frontal Polymerization of Stereoisomers: Distinct Microstructures and Properties in Endo- and Exo-Dicyclopentadiene Thermosets. Macromolecules, 2024, 57, 1, 142-149.
  34. Davydovich, O; Greenlee, A. J.; Root, H. D.; Jansen, A. L.; Gallegos, S. C.; Warner, M. J.; Kent, M. S.; Cardenas, J. A.; Appelhans, L. N.; Roach, D. J.; Jones, B. H.; Leguizamon, S. C. Encapsulated Transition Metal Catalysts Enable Long Term Stability in Frontal Polymerization Resins. Macromolecules, 2023, 56, 18, 7543-7550. 
  35. AlFaraj, Y. S.; Mohapatra, S.; Shieh, P.; Husted, K. E. L.; Ivanoff, D. G.; Lloyd, E. M.; Cooper, J. C.; Dai, Y.; Singhal, A. P.; Moore, J. S.; Sottos, N. R.; Gomez-Bombarelli, R.; Johnson, J. A. A Model Ensemble Approach Enables Data-Driven Property Prediction for Chemically Deconstructable Thermosets in the Low Data Regime. ACS Cent. Sci., 2023, 9, 9, 1810-1819.
  36. Davydovich, O.; Paul, J. E.; Feist, J. D.; Aw, J. E.; Balta Bonner, F. J.; Lessard, J. J.; Tawfick, S.; Xia, Y.; Sottos, N. R.; Moore, J. S. Frontal Polymerization of Dihydrofuran Comonomer Facilitates Thermoset Decontruction. Chemistry of Materials, 2023, 34, 8790-8797. 
  37. Suslick, B. A.; Hemmer, J.; Groce, B. R.; Stawiasz, K. J.; Geubelle, P. H.; Malucelli, G.; Mariani, A.; Moore, J. S.; Pojman, J. A.; Sottos, N. R. Frontal Polymerizations: From Chemical Perspectives to Macroscopice Properties and Applications. Chem. Rev., 2023, 123, 3237-3298.
  38. Suslick, B. A.; Klok, H.-A.; Moore, J. S. There is Signal in Your Noise: A Case for Advanced Mass Analysis. ACS Polym. Au., 2022, 2, 392-396.
  39. Suslick, B. A.; Alzate-Sanchez, D. M.; Moore, J. S. Scalable Frontal Oligomerization: Insights from Advanced Mass Analysis. Macromolecules, 2022, 55, 8234-8241.

REMAT Published Data Sets

  1. Krishnan, P.; Lessard, J. J.; Suslick, B. A.; Cramblitt, A. C.; Balta, J.; Arretche, I. Differential Scanning Calorimetry to Determine Reactivity of Stable Viscosity-modified Thermoset Resins in Frontal Polymerization. Materials Data Facility, 2025.
  2. Cramblitt, A. C.; Lessard, J. J.; Arretche, I. Differential Scanning Calorimetry of Thermosets Polymerized via Chemical Activation of Frontal Ring-Opening Metathesis Polymerization. Materials Data Facility, 2025.
  3. Cramblitt, A. C.; Lessard, J. J.; Arretche, I. Videos of Chemically Activated Frontal Polymerization of Thermosets. Materials Data Facility, 2025.